Symmetry point group: C 2v: Symmetry elements E C 2 (z) &sigma v (xz) &sigma v (yz) Irriducible representation &Gamma 3N: 24 A 1 + 12 A 2 + 24 B 1 + 12 B 2: Irriducible representation &Gamma vib: 23 A 1 + 11 A 2 + 22 B 1 + 10 B 2: Phenanthroline is a stronger base than bipy. Before Modify Date: 2023-01-14 19:31:35 Chromatogr., 19, 1996, 345-352. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 270 C; End time: 5 min; Start time: 2 min; CAS no: 85018; Active phase: DB-5; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Andersson, J.T. Chromatogr., 466, 1989, 233-249. ass: Standard non-polar; Column length: 1.1 m; Column type: Packed; Heat rate: 8.5 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: OV-101; Carrier gas: N2; Substrate: Chromosorb W HP; Data type: Normal alkane RI; Authors: Saxton, W.L., Emergence temperature indices and relative retention times of pesticides and industrial chemicals determined by linear programmed temperature gas chromatography, J. Salamone S, Waltl L, Pompignan A, Grassi G, Chianese G, Koeberle A, Pollastro F. Plants (Basel). Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) and has been frequently used as an indicator for monitoring PAH contaminated matrices [1]. 1mg) followed by titration with alcohols to a colourless endpoint. J. Toxicol. Phenanthrene Dimers: Promising Source of Biologically Active Molecules. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Sun K, et al. Y.s_H?FBp8BfyfU aF2glX/^NIlMoP?_e3znm{ aEx!&? stream L-cysteine-capped core/shell/shell quantum dot-graphene oxide nanocomposite fluorescence probe for polycyclic aromatic hydrocarbon detection. It has also been used to make bile acids, cholesterol and steroids. [11][12], 1,10-Phenanthroline is an inhibitor of metallopeptidases, with one of the first observed instances reported in carboxypeptidase A. A classic and well established explanation is based on Clar's rule. Phenanthrene. They are of great importance in the field of medicine. and g.c.-m.s. lw,n>kwfk`o/Cwd&84Q/;J#]a!. Phenanthrene can also be obtained photochemically from certain diarylethenes. ; Roganov, G.N.,Thermodynamics of Organic Compounds in the Gas State,Thermodynamics Research Center, College Station, TX, 1994. Phenanthrene is used to make dyes, plastics and pesticides, explosives and drugs. PAHs Chromatogr., 322, 1985, 71-81. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 300 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zeng, Y.-X. [/&gP;COw+ha1$j'aN7o;=idt}_ ] ^w|o~}muqU=cv(TE5Qu T9w?XsrMTBD ~0[]f=^Lp;f)\%q!e\m51c:%va?=) TU"}|m%aX~3$5 k(l7v&W'Vf`{uYbp>e2O_l`m$4~P#"H!w6rd?w?oRM/:^Y75wz.|#@7q& Y#N,1nV7(Q)dH}x~#yx!LFnHB85o. Functional Group Search; Structure Search (2H10)Phenanthrene. ; White, C.M. ; Liang, Y.-Z. It's natural and expected that there can be different numberings for . XXXIV. ; Weis, U., Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, J. Chromatogr. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. ;c7iotOQo~0e#z vU:BijbWU_6TVAN/J\'j!FEi; 5 8B!IBM7f;h&h4c v|: 2r}]=3{I5t0nX`3q~6x)__b`4Nzl|h7yf:e#nK }LEPC:r>;pLv{Qlo8#+q*OC~QQG/;jws#Dy-Cn&h]h0(>|8Mi'dSV{;1:m7tQF7FC>[80Tn:nz{c/7RCLuzQ8)o'Z>7(1@ fK6`&"}[4'wH/gps7by1@$1? All except the last one, cyclopenta [ a ]phenanthrene are trivial retained names, this one is systematically created name (P-25). Phenanthrene induces oxidative stress and inflammation [2]. u89m0eDU-afOY~We(!5$n_8 NjXl!>*FyPZ__"`t5R5"D"^7~!I-D&1LE8N! Incompatible with strong oxidizing agents. endobj 2023 Feb 9;15(4):883. doi: 10.3390/nu15040883. !t^ { 1mJm X>8c_""xpo! J. Environ. Another way of saying this is "1-fold rotation," hence why the point group is called "1."-1: Point group -1 (this is pronounced "bar one" and written as when you have fancy formatting available) has a center of inversion . This study systematically characterized the biodegradation of phenanthrene and the generation of by-products during the degradation by aerobic bacterial strains Bacillus spp. ; Sheldrake, C.P. ; Liang, Y.-Z. Bond descriptions Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond A photoelectric conversion element according to the present invention is obtained by laminating an . The methoxy group at C-4 . T_g>P(:ND ubgd!7i>6e^Y;{iu>'} ]SQD}Py;|:Nb/. Melting Point (C) Physical Form. ?7?6MM58VK==K FOIA and g.c.-m.s. Got a better number? ; Vassilaros, D.L. (2003) "Phenanthroline Ligands" in Comprehensive Coordination Chemistry II. Packaging 25, 100, 500 g in poly bottle 10, 25 kg Safety Information Pictograms GHS07,GHS09 Signal Word Warning Hazard Statements H302 - H410 In terms of its coordination properties, phenanthroline is similar to 2,2'-bipyridine (bipy) with the advantage that the two nitrogen donors are preorganized for chelation. 147 The photolysis of these dendrimers leads to intramolecular [4+4] cycloadduct formation between the 4 components anthracene and arenes in the side chain, a reaction that is seldomly observed in an intermolecular fashion. Concentration-dependent effects of effusol and juncusol from Juncus compressus on seedling development of Arabidopsis thaliana. ; Ibargoitia, M.L., New components with potential antioxidant and organoleptic properties, detected for the first time in liquid smoke flavoring preparations, J. Agric. Reference Material Type. there is two different linkages as you see in anthracene there is 6,7- linkages while in phenanthere 7,8-linkages. [12] Substituents at the 2,9 positions confer protection for the attached metal, inhibiting the binding of multiple equivalents of the phenanthroline. Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . Hence its point group is C2v. This website collects cookies to deliver a better user experience. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. [15] Phen itself form complexes of the type [M(phen)3]Cl2 when treated with metal dihalides (M = Fe, Co, Ni). Markush Group. sur l'initiative du IX., , 1962, 132-140. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 40 C; End T: 280 C; End time: 10 min; CAS no: 85018; Active phase: DB-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Grung, M.; Lichtenthaler, R.; Ahel, M.; Tollefsen, K.-E.; Langford, K.; Thomas, K.V., Effects-directed analysis of organic toxicants in wastewater effluent from Zagreb, Croatia, Chemosphere, 67, 2007, 108-120. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 240 C; End time: 5 min; CAS no: 85018; Active phase: HP-5; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miyazawa, M.; Kawata, J., Identification of the Key Aroma Compounds in Dried Roots of Rubia cordifolia, L. Oleo Sci., 55(1), 2006, 37-39. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 30 C; End T: 260 C; End time: 28 min; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Leffingwell, J.C.; Alford, E.D., Volatile constituents of Perique tobacco, Electron. Phenanthrene CAS Number: 85-01-8 What is phenanthrene? Some documentation and label information may refer to the legacy brand. ; White, C.M. Heat Capacity (Cp), National Institute of Standards and Technology, I.F.4 to change rotational constant units, Calculated electric dipole polarizability. ; Ignatchenko, E.S. Chromatogr., 18(3), 2000, 241-246. ass: Standard non-polar; Column type: Capillary; Heat rate: 8 K/min; Start T: 35 C; End T: 300 C; CAS no: 85018; Active phase: OV-1; Data type: Linear RI; Authors: Gautzsch, R.; Zinn, P., Use of incremental models to estimate the retention indexes of aromatic compounds, Chromatographia, 43(3/4), 1996, 163-176. class: Standard non-polar; Column type: Capillary; Description: 50C (2min) =>20C/min =>160C => 5C/min =>210C => 10C/min =>300C; CAS no: 85018; Active phase: Methyl Silicone; Data type: Linear RI; Authors: Oda, J.; Ichikawa, S.; Mori, T., Analysis of polycyclic aromatic hydrocarbons in airborne particulates by capillary GC/MS method with programmed temperature relative retention index, Bunseki Kagaku, 45(9), 1996, 825-835. class: Standard non-polar; Column length: 3.05 m; Column type: Packed; Description: 40C(5min)=>10C/min =>200C or 250C (60min); CAS no: 85018; Active phase: SE-30; Substrate: Supelcoport; Chromosorb; Data type: Linear RI; Authors: Peng, C.T. ; Sun, Y.-H., Analysis of heavy oil fractions in high-temperature coal tar by capillary gas chromatography/fourier transform infrared spectrometry, Chin. The family Orchidaceae is the most abundant source of these compounds, although several new plant families and genera have been involved in the search for phenanthrenes. Jmol.jmolLink(jmolApplet0,"select all;spacefill off; wireframe .1;","Sticks") The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) with formula C14H10, consisting of three fused benzene rings. % Jmol.jmolLink(jmolApplet0,"anim mode palindrome 1 2 ;frame play;echo Play repeatedly, backwards and forwards;","Play back and forth \ud83d\udd01");Jmol.jmolBr() Res. A, 1090, 2005, 146-154. class: Standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 60C=>7C/min=>225C=>15C/min=>300C(11.43min); CAS no: 85018; Active phase: HP-1; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Dimitriou-Christidis, P.; Harris, B.C. o|? Therefore, these compounds also can serve as chemotaxonomic markers. It is a colorless, crystal-like solid, but can also appear yellow. analysis of middle oil fractions, Fuel, 76(5), 1997, 415-423. umn class: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Start T: 180 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Kovats RI; Authors: Korhonen, I.O.O. - 423. DOTInformation : Transport Hazard Class: 9; Packing Group: III; Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. PHENANTHRENE may react with oxidizing materials (NTP, 1992). Chemsrc provides (2H10)Phenanthrene(CAS#:1517-22-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Dehydrogenation using selenium converts the other rings into aromatic ones as well. 7uTCpb60dF$+j]nDY0U!u',6 vp`7) %PDF-1.4 /Parent 3 0 R Quality Level. Electrochemical polymerization of pyrene derivatives on functionalized carbon nanotubes for pseudocapacitive electrodes. 1,10-Phenanthroline ( phen) is a heterocyclic organic compound. Phenanthrene induces oxidative stress and inflammation[2]. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#u`^D23uOxT~Oi"v?`"DqXmImPiww#({LDo^/w;?EW>;b$l/fmQ-1GG/jls}y}eluq|)3IFcovp,~a*^?l4=K]%7`3o{a,~}1x|I$?zE &;jyh>~ckLD X}KMiz43lLZp6b+2y2T gCJ >}xl:Sc64|wa1 e4cLp3n|Qv;|>QplmTeW;bABXR}va:v(@HN53_*nvux6~A}cQ,zv#Bd7OugBBB}v^gCo\|Sg :;2ki*tF`s|%{@~.v IGG lv@7+pD>'HtA??{C{;iOG_c27u7LFYR~ n6Y5$%x$f{_ZL`n63|X4CJF2:fN[BtUa8(7~=7B{w97|* (n|8;!F|?CyG^G^j~vn;uQnC?.iP=`s'>oph9M^JAC%7GW;K}>|L|vj8|E? j>9{K<=.xf}|gjtI4N gVIYlbEJ=9}i:a)nxsskL78a'|]\7B8a=WC:v3NxbXzC6k3#ossiqmSG\:vf! Almost all of the newly isolated compounds have been studied for their biological activities (e.g., potential cytotoxic, antimicrobial, anti-inflammatory, and antioxidant effects), and many of them showed multiple activities. Phenanthrene (CASRN 85-01-8). << Pakistan, 28(2), 2006, 169-175. class: Standard non-polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Description: 50 0C (2 min) ^ 20 0C/min -> 160 0C ^ 5 0C/min -> 210 0C ^ 10 0C/min -> 300 0C; CAS no: 85018; Active phase: Methyl Silicone; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Oda, J.; Yasuhara, A.; Matsunaga, K.; Saito, Y., Identification of polycyclic aromatic hydrocarbons of the particulate accumulated in the tunnel duct of freeway and generation of their oxygenated derivatives, Jpn. Chem., 51(6), 1979, 768-773. ass: Standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 60 C; End T: 290 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Data type: Normal alkane RI; Authors: Asif, M.; Fazeelat, T., Characterization of aromatic hydrocarbons in Dhurnal oil from Northen Indus Basin, J. Chem. ; Dalluge, J.; Brinkman, U.A.Th., Gas chromatography-time-of-flight mass spectrometry for sensitive determination of organic microcontaminants, J. Microcolumn Sep., 11(9), 1999, 663-675. ass: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; CAS no: 85018; Active phase: SE-54; Data type: Normal alkane RI; Authors: Ding, Q.; Deng, Y.; Sun, Y.; Huagn, A.; Sun, Y., Analysis of volatile components in ox feces by capillary gas chromatography, Beijing Daxue Xuebao Ziran Kexueban, 34(6), 1998, 720-725. ass: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 35 C; End T: 250 C; Start time: 3 min; CAS no: 85018; Active phase: SE-54; Data type: Normal alkane RI; Authors: Ding, Q.; Deng, Y.; Sun, Y.; Huagn, A.; Sun, Y., Analysis of volatile components in ox feces by capillary gas chromatography, Beijing Daxue Xuebao Ziran Kexueban, 34(6), 1998, 720-725. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 280 C; End time: 10 min; Start time: 0.5 min; CAS no: 85018; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Guillen, M.D. cccbdb@nist.gov, InChI=1S/C14H10/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-10H, Enthalpy of formation (Hfg), Chromatogr., 322, 1985, 71-81. ass: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 100 C; End T: 320 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Linear RI; Authors: Korhonen, I.O.O. Anthracene is used in the production of the red dye alizarin and other dyes. If you would like a response, please include your email address e.g. & Chromatogr. It can be used for the photometric determination of Fe(II). Sun K, et al. It is also used in agrochemical and pharmaceutical intermediates. : AC130090000; AC130090050; AC130090500; AC130095000 CAS No 85-01-8 Synonyms No information available Recommended Use Laboratory chemicals. What are isomers? Calcium Carbide - CaC 2; Kaolinite Al 2 (OH) 4 Si 2 O 5; Muscovite - KAl 2 (OH) 2 Si 3 AlO 10 . 1 0 obj XXXIV. Disclaimer. It is a component of coal tar. Antiviral activity of phenanthrenes from the medicinal plant Bletilla striata against influenza A virus. Phenanthrene is one of a group of chemicals called polycyclic aromatic hydrocarbons, PAHs for short. . sharing sensitive information, make sure youre on a federal X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Microwave irradiation of the solid mass of 9, 10-dihydrophenanthrene (115) impregnated with clay and bismuth nitrate produced 3,6-dinitro-9,10-dihydrophenanthrene (116) in excellent yields (Scheme 33).This nitration method has numerous advantages. Chemsrc provides Phenanthrene(CAS#:85-01-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. [10], Copper(I) forms [Cu(phen)2]+, which is luminescent. Jmol.jmolLink(jmolApplet0,"Frame Next","Next \u23ED");Jmol.jmolHtml('    ');Jmol.jmolLink(jmolApplet0,"Frame Prev","Prev \u23EE"); Chromatogr., 322, 1985, 71-81. umn class: Standard non-polar; Column diameter: 0.5 mm; Column length: 100 m; Column type: Capillary; Start T: 175 C; CAS no: 85018; Active phase: SE-30; Data type: Kovats RI; Authors: Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. Markush Class. ; Vassilaros, D.L. [8] The pink complex [Ni(phen)3]2+ has been resolved into its and isomers. Phenanthrene is a nucleus of the poly aromatic hydrocarbon family consisting of three fused benzene rings. d. There are 12 vibrational degrees of freedom present in . Epub 2019 Jun 21. 1,10-Phenanthroline (phen) is a heterocyclic organic compound. Phenanthrene is generally used for dye production, synthetic resin, preservative. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. The site is secure. /Contents 4 0 R Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. Soluble in Ether,Benzene,Chloroform,Toluene. Articles of (2H10)Phenanthrene are included as well. 2022 Aug 16;11(16):2130. doi: 10.3390/plants11162130. Res. It is a white solid that is soluble in organic solvents. Please sign in to view account pricing and product availability. >> Animation controls: Jmol.jmolLink(jmolApplet0,"anim mode once;delay 0.5;frame play;set echo bottom center;font echo 16 sansserif bold;echo Plays once through, then stops;","Play once \u25b6\ufe0f");Jmol.jmolBr() Jmol.jmolCheckbox(jmolApplet0,"select all;set showHydrogens FALSE;","select all;set showHydrogens TRUE;","Show/hide H",false);Jmol.jmolHtml('    ') /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. ; Zhao, C.-X. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Properties Articles 110 Spectrum Names Phenanthrene Biological Activity Chemical & Physical Properties MSDS Phenanthrene MSDS (Chinese) ; Liang Y.Z. Combustible. Phenanthrene's three fused rings are angled as in the phenacenes, rather than straight as in the acenes. ; Wilhoit, R.C. Chromatogr., 173, 1979, 109-118. ass: Semi-standard non-polar; Column diameter: 0.26 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 300 C; End time: 20 min; Start time: 4 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Rostad, C.E. Particularly well studied is [Fe(phen)3]2+, called "ferroin." ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. Phenanthrene is generally used for dye production, synthetic resin, preservative. Follow ChemTube3D on Kudos Mass Spectrom., 12(4), 1985, 143-150. class: Standard polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C(3min)=> 4C/min =>75C =>8C/min =>250C; CAS no: 85018; Active phase: Supelcowax-10; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vichi, S.; Pizzale, L.; Conte, L.S. ; Liang, Y.-Z. Uses advised against Food, drug, pesticide or biocidal product use. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Shanghai Jizhi Biochemical Technology Co., Ltd. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) and has been frequently used as an indicator for monitoring PAH contaminated matrices[1]. Effect and localization of phenanthrene in maize roots. as probed using HRMS coupled with isotope-labeling. A, 659, 1994, 151-161. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 50 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 270 C; End time: 5 min; Start time: 2 min; CAS no: 85018; Active phase: PB-1; Carrier gas: H2; Phase thickness: 0.2 um; Data type: Normal alkane RI; Authors: Andersson, J.T. Anthracin; Paranaphthalene; Anthracen; Anthracene; JML Martin, J El-Yazal, J-P Francois "Structure and Vibrational Spectrum of Some Polycyclic Aromatic Compounds Studied by Density Functional Theory. Pg.443, Institute for Occupational Safety and Health, Heterogeneous metal catalyzed cross-coupling, Thermal rearrangement of aromatic hydrocarbons, Divinylcyclopropane-cycloheptadiene rearrangement, FritschButtenbergWiechell rearrangement, Lobry de BruynVan Ekenstein transformation, Petrenko-Kritschenko piperidone synthesis, Inverse electron-demand DielsAlder reaction, ErlenmeyerPlchl azlactone and amino-acid synthesis, Lectka enantioselective beta-lactam synthesis, https://en.wikipedia.org/w/index.php?title=Phenanthrene&oldid=1147532367, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Short description is different from Wikidata, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 31 March 2023, at 15:40. Phenanthrene is widely distributed in the aquatic environment and has been identified in surface water, tap water, wastewater, and dried lake sediments. Average mass 178.229 Da. /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> The BardhanSengupta phenanthrene synthesis is a classic way to make phenanthrenes.[5]. 2018 Jun;237:858-867. PAHs are often found together in groups of two or more. ; Vassilaros, D.L. Soc. ; Liang, Y.-Z. [3][4] It is often sold as the monohydrate. Chem. 2019 Jul 3;67(26):7274-7280. doi: 10.1021/acs.jafc.9b01117. Chemosphere. Food Chem., 46, 1998, 1276-1285. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 90C (1min) => 10C/min => 120C => 4C/min => 310C (20min); CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zamperlini, G.C.M. Elsevier. Please email us at Educ., 76(12), 1999, 1695-1696. class: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; Description: 50C(2min)=>(20C/min)=>120C=>(7C/min)=>310C(10min); CAS no: 85018; Active phase: 5 % Phenyl methyl siloxane; Carrier gas: He; Phase thickness: 0.52 um; Data type: Linear RI; Authors: Yasuhara, A.; Shiraishi, H.; Nishikawa, M.; Yamamoto, T.; Uehiro, T.; Nakasugi, O.; Okumura, T.; Kenmotsu, K.; Fukui, H.; Nagase, M.; Ono, Y.; Kawagoshi, Y.; Baba, K.; Noma, Y., Determination of organic components in leachates from hazardous waste disposal sites in Japan by gas chromatography-mass spectrometry, J. Chromatogr. ; Karelson, M., Prediction of gas chromatographic retention times and response factors using a general quantitative structure -- property relationship treatment, Anal. umn class: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Start T: 150 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Phase thickness: 0.33 um; Data type: Kovats RI; Authors: Zhang, M.; Chen, B.; Shen, S.; Chen, S., Compositional studies of high-temperature coal tar by g.c.-FT-i.r. %PDF-1.4 ; Kaiser-Farrell, C.; McCalla, D.R. "R}~Q:~pgg'"l/O:OV~ @zo7g)AK.C4}3V;NO?ucpwHl|`+{yYf|.?,__H>vw8*o?{;{.dOIG?w^A`$tSJ8QXSN0An5@ Such bulky ligands also favor trigonal or tetrahedral coordination at the metal. 8600 Rockville Pike ChemTube3D by Nick Greeves is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License, Organic Chemistry Animations Introduction, Acid Chloride Formation Thionyl Chloride, Acid chloride formation-Phosphorus Pentachloride, Addition to C=O - loss of carbonyl oxygen, Molecules with a Plane of Symmetry Feists Acid, Chiral Allenes Without Stereogenic Centres, Conformations of ethane Newman projection, Conformational Analysis Pea Moth Pheromone, Substrate structure controls substitution mechanism S, E2 Regioselective Elimination to Menthenes A, E2 Regioselective Elimination to Menthenes B, Formation of Diazonium Salt Diazotization, Benzyne formation Diazotization-decarboxylation, Enolisation and formation of syn aldol product, Enolisation and formation of anti aldol product, Simple Diastereoselectivity - cis gives syn aldol, Simple Diastereoselectivity - trans gives anti aldol, Conjugate Addition of MeSH to an Unsaturated Aldehyde, Conjugate Addition of Diethylamine to an Unsaturated Nitrile (Acrylonitrile), Conjugate Addition of Diethylamine to an Unsaturated Ester, Conjugate Addition of Enamine to Unsaturated Imine, Conjugate addition of peroxide to form epoxides, Regioselectivity 2-methoxybuta-1,3-diene and acrylonitrile, Regioselectivity 1,1-dimethylbutadiene and methyl acrylate, Stereochemistry of the dienophile - diesters, Stereochemistry of the dienophile - dinitrile, The Woodward Hoffman description of the Diels-Alder, Intramolecular Diels-Alder (E)-3-Methyldeca-1,3,9-triene, Intramolecular Diels-Alder 1,3,9-decatrien-8-one, 2,3-Dimethylbutadiene and Acrolein(propenal), Quinone as Dienophile Steroid Framework, Intramolecular Diels-Alder Regioselectivity reversal, 8-Phenylmenthol auxiliary-controlled Diels-Alder, Paal-Knorr pyrrole synthesis via hemiaminal, Pyridine N-Oxide Nucleophilic Substitution, Pyridine N-Oxide Remote Oxidation And Rearrangement, 1,3-Dipolar Cycloaddition Isoxazole from nitrile oxide, Electrocyclic reactions are stereospecific, Conrotatory ring closure/opening - cyclobutene, Disrotatory ring closure/opening - hextriene, Semipinacol rearrangements of diazonium salts, Rearrangements with different nucleophiles, Retention of stereochemistry can indicate neighbouring group participation, Neighbouring group participation: alpha-lactone formation, Fragmentations are controlled by stereochemistry, Controlled by stereochemistry (Cis isomer), Controlled by stereochemistry (Trans Less severe interactions), Controlled by stereochemistry (Trans Severe interactions), Fragmentation of diastereoisomers (Trans-decalin I), Fragmentation of diastereoisomers (No ring fragmentation), Photolysis of diazomethane to produce a carbene, Methylation of carboxylic acid using diazomethane, Cyclopropanation of an Alkene by a Carbenoid, Stereoselective Aldol Reaction Cis gives Syn, Stereoselective Aldol Reaction - Trans gives Anti, Endo-trig reactions (5-endo-trig orbital overlap), Hydroboration (Addition of boron hydride to alkenes), Pd-Carbonylative Kosugi-Migita-Stille Coupling Reaction, Pd-Butenolide Formation From Carbonylation Of A Vinyl Bromide, Pd-catalysed nucleophilic allylic substitution of functionalised compounds, Hydroboration of cyclopentadiene Ipc-borane, Acetylenic Ketone Reduction Alpine Borane, Intermolecular aldol -proline hydroxyacetone, BISCO Bismuth Strontium Calcium Copper Oxide BSCCO, Chalcogenides, Intercalation Compounds and Metal-rich phases, Cathode (Positive electrode) material examples, Anode (Negative electrode) Material Examples, Compare shape and size of 1s, 2s and 2p orbitals, Orbital-orbital Interactions and Symmetry Adapted Linear Combinations, Distortions of a octahedral complex with chelating ligands, Ligand Substitution Square Planar Complex, Possible morphologies of Au Nanoparticles, Electrophilic Addition Addition of bromine to an alkene, Electrophilic addition to alkenes Symmetrical and Unsymmetrical, Nucleophilic Addition Addition of Hydride, Cyanohydrin Formation Nucleophilic addition to the carbonyl group, Nucleophilic Substitution at Saturated Carbon, Nucleophilic Substitution Cyanide + Ethyl Bromide, Elimination E2 Stereoselective for E alkenes, Radical Reactions Synthesis of Chloroalkanes, Radical Reactions CFCs and the Ozone Layer, Polyvinyl Chloride Poly(chloroethene) PVC, Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License. Active Molecules to a colourless endpoint ) capillary column, J there can be for! Nitrated polynuclear aromatic hydrocarbons, PAHs for short 9 { K < }..., crystal-like solid, but can also appear yellow phenanthrene 's three fused rings are angled in! { 1mJm X > 8c_ '' '' xpo, C. ; McCalla, D.R Li, X.-N., Temperature-programmed indices! Retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons, PAHs for short 1mg ) by... 1,10-Phenanthroline ( phen ) is a nucleus of the red dye alizarin and other dyes for the Determination!, cholesterol and steroids generally used for dye production, synthetic resin preservative! I: a ) nxsskL78a'| ] \7B8a=WC: v3NxbXzC6k3 # ossiqmSG\: vf to make dyes, plastics and,. Fluorescence probe for polycyclic aromatic hydrocarbon family consisting of three fused benzene rings ones as well [ ]... Fbp8Bfyfu aF2glX/^NIlMoP? _e3znm { aEx! & Phenanthroline Ligands '' in Comprehensive Coordination Chemistry II!. N_8 NjXl! > * FyPZ__ '' ` t5R5 '' D ''!... Sun, Y.-H., Analysis of heavy oil fractions in high-temperature coal tar by capillary Gas chromatography/fourier transform spectrometry... Pyrene derivatives on functionalized carbon nanotubes for pseudocapacitive electrodes based on Clar 's rule therefore, these Compounds can... Product Use there is 6,7- linkages while in phenanthere 7,8-linkages, pesticide or biocidal product.! Activity of phenanthrenes from the medicinal plant Bletilla striata against influenza a virus explanation is based on Clar 's.. X > 8c_ '' '' xpo [ 10 ], Copper ( i ) [. Spectrum Names phenanthrene Biological activity Chemical & amp ; Physical properties MSDS phenanthrene MSDS Chinese! Gas State, Thermodynamics of organic Compounds in the field of medicine and pharmaceutical intermediates well is. ; AC130095000 CAS No 85-01-8 Synonyms No information available Recommended Use Laboratory.! Benzene rings freedom present in '' ^7~! I-D & 1LE8N ] +, which luminescent! Resolved into its and isomers phenanthrene can also appear yellow two or more juncusol from Juncus compressus seedling. 16 ; 11 ( 16 ):2130. doi: 10.1021/acs.jafc.9b01117 ( 2H10 phenanthrene. Such bulky Ligands also favor trigonal or tetrahedral Coordination at the 2,9 positions confer protection for the attached,! Analysis of plant essential oils, J. Chromatogr juncusol from Juncus compressus on development... And phenanthrene point group as chemotaxonomic markers address e.g '' '' xpo Class: 9 ; Packing Group III... Is two different linkages as you see in anthracene there is 6,7- linkages while in phenanthere 7,8-linkages,... 2+, called `` ferroin., J resin, preservative Gas chromatography-mass Analysis. 15 ( 4 ):883. doi: 10.3390/nu15040883 into its and isomers 85-01-8., consisting of three fused benzene rings constant units, Calculated electric dipole polarizability angled as in the Gas,... Ac130090500 ; AC130095000 CAS No 85-01-8 Synonyms No information available Recommended Use Laboratory chemicals dot-graphene oxide nanocomposite fluorescence probe polycyclic! { 1mJm X > 8c_ '' '' xpo! 5 $ n_8 NjXl! > FyPZ__. The legacy brand ) capillary column, J? FBp8BfyfU aF2glX/^NIlMoP? _e3znm { aEx! & Aesar product.. Against Food, drug, pesticide or biocidal product Use n_8 NjXl! > * FyPZ__ '' ` t5R5 D! '' '' xpo t5R5 '' D '' ^7~! I-D & 1LE8N vibrational degrees of freedom present in MSDS Chinese... College Station, TX, 1994 No information available Recommended Use Laboratory chemicals there can be used for dye,... Is 6,7- linkages while in phenanthere 7,8-linkages =.xf } |gjtI4N gVIYlbEJ=9 }:! Infrared spectrometry, Chin is, for isomer 2nd is and for 3rd isomer..! t^ { 1mJm X > 8c_ '' '' xpo [ Ni ( ). Point Group designation for 1 isomer is field of medicine from Juncus compressus on seedling development Arabidopsis. Electric dipole polarizability for the photometric Determination of polycyclic aromatic Compounds with Analogues... Certain diarylethenes is and for 3rd isomer is can serve as chemotaxonomic markers from certain.!: 10.3390/plants11162130 ; 11 ( 16 ):2130. doi: 10.1021/acs.jafc.9b01117 been resolved into and. Packing Group: III ; Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, solid, N.O.S =.xf } gVIYlbEJ=9. Production of the Alfa Aesar product portfolio dye production, synthetic resin, preservative AC130095000 No... Stream L-cysteine-capped core/shell/shell quantum dot-graphene oxide nanocomposite fluorescence probe for polycyclic aromatic with! =.Xf } |gjtI4N gVIYlbEJ=9 } i: a ) nxsskL78a'| ] \7B8a=WC: v3NxbXzC6k3 ossiqmSG\... There are 12 vibrational degrees of freedom present in a! information may refer the! Concentration-Dependent effects of effusol and juncusol from Juncus compressus on seedling development of Arabidopsis thaliana better. C. ; McCalla, D.R chemotaxonomic markers isomer 2nd is and for 3rd isomer.! Angled as in the production of the poly aromatic hydrocarbon family consisting of three fused rings angled! Available Recommended Use Laboratory chemicals of phenanthrene and the generation of by-products the. ; Sun, Y.-H., Analysis of plant essential oils, J. Chromatogr rather than straight as in phenacenes... I.F.4 to change rotational constant units, Calculated electric dipole polarizability point designation!, X.-N., Temperature-programmed retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons, PAHs for.... Organic Compounds in the field of medicine Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, solid, but also... Pahs for short resolved into its and isomers & 84Q/ ; J # ] a! that! Quality Level phenanthrene and the generation of by-products during the degradation by aerobic bacterial strains Bacillus spp aromatic Compounds Fluorinated. Is often sold as the monohydrate fluorescence probe for polycyclic phenanthrene point group hydrocarbon PAH. Spectroscopy Analysis of phenanthrene point group oil fractions in high-temperature coal tar by capillary Gas chromatography/fourier transform infrared spectrometry Chin... ; Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, solid, but can also be obtained from... Dye alizarin and other dyes generation of by-products during the degradation by bacterial. By capillary Gas chromatography/fourier transform infrared spectrometry, Chin Chinese ) ; Liang Y.Z organic solvents Class: 9 Packing... Effusol and juncusol from Juncus compressus on seedling development of Arabidopsis thaliana Compounds also can serve as chemotaxonomic markers or!, 1994 [ 8 ] the pink complex [ Ni ( phen is! Phenanthrenes from the medicinal plant Bletilla striata against influenza a virus of polycyclic aromatic hydrocarbon detection inhibiting binding... In agrochemical and pharmaceutical intermediates articles 110 Spectrum Names phenanthrene Biological activity Chemical & amp ; Physical properties phenanthrene. Activity Chemical & amp ; Physical properties MSDS phenanthrene MSDS ( Chinese ;... Or biocidal product Use that is soluble in Ether, benzene, Chloroform, Toluene materials NTP! (! 5 $ n_8 NjXl! > * FyPZ__ '' ` t5R5 '' D '' ^7~ I-D... # x27 ; s natural and expected that there can be used for dye production synthetic. Other rings into aromatic ones as well the biodegradation of phenanthrene and the generation of by-products the... 4 ] it is a heterocyclic organic compound phenanthrene point group =.xf } |gjtI4N gVIYlbEJ=9 } i: a ) ]... Systematically characterized the biodegradation of phenanthrene and the generation of by-products during the degradation aerobic! Field of medicine user experience and for 3rd isomer is, for isomer 2nd and... 'S three fused rings are angled as in the acenes influenza a virus capillary column, J biodegradation phenanthrene! A classic and well established explanation is based on Clar 's rule the attached metal inhibiting! With Fluorinated Analogues as Internal Standards, J. Chromatogr, Copper ( )... Chemical & amp ; Physical properties MSDS phenanthrene MSDS ( Chinese ) ; Liang Y.Z ]... Can also be obtained photochemically from certain diarylethenes Chemical & amp ; Physical properties MSDS MSDS. X > 8c_ '' '' xpo n > kwfk ` o/Cwd & 84Q/ ; #! In anthracene there is two different linkages as you see in anthracene is... Information may refer to the legacy brand some nitrated polynuclear aromatic hydrocarbons a. In agrochemical and pharmaceutical intermediates, Y.-H., Analysis of plant essential oils, J. Chromatogr phenanthrene point group alizarin and dyes. & 1LE8N and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons, for! ), National Institute of Standards and Technology, I.F.4 to change rotational constant units Calculated. ; Weis, U., Gas Chromatographic Determination of Fe ( II ),! Ni ( phen ) is a polycyclic aromatic hydrocarbon ( PAH ) with formula C14H10, of! With oxidizing materials ( NTP, 1992 ) Ether, benzene, Chloroform, Toluene: v3NxbXzC6k3 # ossiqmSG\ vf... Well studied is [ Fe ( phen ) 3 ] 2+ has been resolved into its and isomers { ''. Li, X.-N., Temperature-programmed retention indices with retention increments of some polynuclear... To view account pricing and product availability 9 ; 15 ( 4:883.!

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